Fabrikasi Magnet MnZn Ferit dan Barium Ferit dari Limbah Pengelasan
DOI:
https://doi.org/10.14203/jet.v15.14-17Keywords:
MnZn ferit, Barium ferit, limbah pengelasanAbstract
Pembuatan magnet lunak MnZn ferit dan magnet keras barium ferit telah dilakukan menggunakan bahan baku utama limbah pengelasan. Limbah pengelasan yang digunakan merupakan limbah dengan komposisi utama Fe dan O dengan Al dan Bi sebagai pengotor. Magnet dipabrikasi menggunakan metode metalurgi serbuk, yang diawali dengan penggilingan selama 6 jam untuk mendapatkan serbuk, dilanjutkan dengan pemanggangan pada 560 °C selama 1 jam untuk mendapatkan fasa hematit. Karakterisasi XRD (x-ray diffraction) menggunakan analisa Rietveld menunjukkan hematit 73,4% berat telah terbentuk setelah pemanggangan dengan fasa magnetik sebesar 26,6% berat. Serbuk setelah pemanggangan digunakan sebagai bahan baku magnet ferit dengan ditambahkan senyawa penyusun kation dan aditif. Perhitungan stoikiometri bahan baku yang digunakan pada penelitian ini didasarkan pada rumus kimia Mn0,8Zn0,2Fe2O4 dan BaFe12O19. Melalui karakterisasi menggunakan Permagraph, pembuatan magnet menggunakan limbah pengelasan didapatkan sifat magnetik untuk MnZn ferit adalah induksi remanen 0,83 kG dengan koersifitas 0,084 kOe dan untuk barium ferit memiliki induksi remanen 1,22 kG dengan koersifitas 2,996 kOe.
Downloads
References
S. Kanazawa, N. Takahashi, and T. Kubo, “Measurement and analysis of AC loss of NdFeB sintered magnet”, Electrical Engineering in Japan, vol. 154 (4), pp. 8-15, 2006.
J. G. Lee, J. H. Kim, K. P. Chae, “Crystallographic and Magnetic Properties of Zn-Mn Ferrite”, Journal of the Korean Physical Society, vol. 49 (2), pp. 604-607, 2006.
The Ceramic Society of Japan, “Automobile Engines and Car Electronics, in Advanced Ceramic Technologies and Product, 1st ed, Y. Imanaka, Tokyo, Japan: Springer Japan, 2012, 301.
P. S. Neelakanta, Handbook of Electromagnetic Materials: Monolithic and Composite Versions and Their Applications, 1st ed, Florida, United States of America: CRC Press, 1995, 347.
W. D. Callister Jr., Material Science and Engineering: An Introduction, 7th ed, United States of America: John Wiley & Sons, Inc., 2007, w39.
A. Ataie, S. Heshmati-Manesh and H. Kazempour, “Synthesis of barium hexaferrite by the co-precipitation method using acetate precursor”, Journal of Material Science, vol. 37 (10), pp. 2125-2128, 2002.
J. Ding, P. G. McCormick, R. Street, “Formation of spinel Mn-ferrite during mechanical alloying”, Journal of Magnetism and Magnetic Materials, vol. 171(3), pp. 309-314, 1997.
K. V. P. M. Shafi, A. Gedanken, R. Prozorov, J. Balogh, “Sonochemical Preparation and Size-Dependent Properties of Nanostructured CoFe2O4 Particles”, Chemistry of Materials, vol. 10 (11), pp. 3445-3450, 1998.
Y. P. Fu, K. Y. Pan, C. H. Lin, “Microwave-induced combustion synthesis of Ni0.25Cu0.25.Zn0.5 ferrite powders and their characterizations”, Material Letters, vol. 57 (2), pp. 291-296, 2002.
K. Nejati, R. Zabihi, “Preparation and magnetic properties of nano size nickel ferrite particles using hydrothermal method”, Chemistry Central Journal, vol. 6 (no. 23), pp. 1-6, 2012.
Y. Y. Meng, M. H. He, Q. Zeng, D. L. Jiao, S. Shukla, R. V Ramanujan, Z. W. Liu, “Synthesis of barium ferrite ultrafine powders by a sol–gel combustion method using glycine gels”, Journal of Alloys and Compounds, vol. 583, pp. 220-225, 2014.
A. Kosak, D. Makovec, A. Znidarsic, M. Drofenik, “Preparation of MnZn-ferrite with microemulsion technique, Journal of the European Ceramic Society, vol. 24 (6), pp. 959-962, 2004.
E. R. Monazam, R. W. Breault, R. Siriwardane, “Kinetics of Magnetite (Fe3O4) Oxidation to Hematite (Fe2O3) in Air for Chemical Looping Combustion”, Industrial & Engineering Chemistry Research, vol. 53 (34), pp. 13320-13328, 2014.
R. Y. Chen, W. Y. D. Yuen, "Oxide-Scale Structures Formed on Commercial Hot-Rolled Steel Strip and Their Formation Mechanism", Oxidation of Metals, vol. 56, pp. 89-118, 2001.
(2015) The Integrated Magnetics website. [Online]. Available: http://www.intemag.com/magnetic_properties.html#Ferrite_(Ceramic)_-_Magnetic_Properties_ .
Downloads
Published
Issue
Section
License
Authors who publish with this journal agree to the following terms:
The copyright to this article is transferred to BRIN if and when the article is accepted for publication. The undersigned hereby transfers any and all rights in and to the paper including without limitation all copyrights to BRIN. The undersigned hereby represents and warrants that the paper is original and that he/she is the author of the paper, except for material that is clearly identified as to its original source, with permission notices from the copyright owners where required. The undersigned represents that he/she has the power and authority to make and execute this assignment. The copyright transfer form can be downloaded here.
The corresponding author signs for and accepts responsibility for releasing this material on behalf of any and all co-authors. This agreement is to be signed by at least one of the authors who have obtained the assent of the co-author(s) where applicable. After submission of this agreement signed by the corresponding author, changes of authorship or in the order of the authors listed will not be accepted.

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.


